Anion metathesis in ionic silica nanoparticle networks

Marco Litschauer (Korresp. Autor*in), Michael Puchberger, Herwig Peterlik, Marie Alexandra Neouze

Veröffentlichungen: Beitrag in FachzeitschriftArtikelPeer Reviewed

Abstract

Metathesis reactions in acetone were performed on ionic silica networks based on imidazolium chloride bridging units. The salts investigated were NaBF4, KPF6 and LiN(SO2CF3)(2). XRD experiments and NMR analysis were used to follow the anion metathesis. For all compounds the thermal stability of the hybrid material was maintained after metathesis. SAXS experiments confirmed that the anion metathesis only very slightly affected the short-range order of the network. However, the yield of the metathesis reaction, depending on the length of the imidazolium based ligand, was evaluated by EDX analyses. The anion metathesis reaction provides a tailoring tool for hybrid material hydrophobicity.
OriginalspracheEnglisch
Seiten (von - bis)1269-1276
Seitenumfang8
FachzeitschriftJournal of Materials Chemistry
Jahrgang20
Ausgabenummer7
DOIs
PublikationsstatusVeröffentlicht - 2010

ÖFOS 2012

  • 1030 Physik, Astronomie
  • 103009 Festkörperphysik
  • 210006 Nanotechnologie

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