Barrier trees of degenerate landscapes

Veröffentlichungen: Beitrag in FachzeitschriftArtikelPeer Reviewed

Abstract

The heights of energy barriers separating two (macro-)states are useful for estimating transition frequencies. In non-degenerate landscapes the decomposition of a landscape into basins surrounding local minima connected by saddle points is straightforward and yields a useful definition of macro-states. In this work we develop a rigorous concept of barrier trees for degenerate landscapes. We present a program that efficiently computes such barrier trees, and apply it to two well known examples of landscapes.
OriginalspracheEnglisch
Seiten (von - bis)155-173
Seitenumfang19
FachzeitschriftZeitschrift für Physikalische Chemie / International Journal of Research in Physical Chemistry and Chemical Physics
Jahrgang216
Ausgabenummer2
PublikationsstatusVeröffentlicht - 2002

ÖFOS 2012

  • 1040 Chemie

Zitationsweisen