Effect of V Content on the Microstructure and Mechanical Properties of High-Pressure Torsion Nanostructured CoCrFeMnNiV_x High-Entropy Alloys

The article presents investigations of microstructure and low-temperature mechanical properties of nanostructured alloys CoCrFeMnNiV_x (x = 0.15–0.75), processed by high-pressure torsion (HPT) at temperatures of 300 and 77 K. While at x ≥ 0.5 the values of microhardness (H_v) and compression yield stress (σ_0.2) in samples after HPT at 77 K are larger than those in samples after HPT at 300 K, for x ≤ 0.2 surprisingly the opposite effect is observed. As in case of the undeformed CoCrFeMnNiV_x alloys, the behavior for vanadium concentrations x ≥ 0.5 can be related to the formation of tetragonal σ-phase in addition to face-centered cubic matrix, while the anomalous behavior for x ≤ 0.2 arises from the formation of HPT-induced hexagonal martensitic phase. In the low-temperature ranges, i.e., 20–300 K in case of HPT nanostructured CoCrFeMnNiV_0.2, and 150–300 K in case of HPT nanostructured CoCrFeMnNiV_0.5, dependences of σ_0.2(T) show characteristics of thermally activated dislocation movement. For the first time in high-entropy alloys, anomalous dependences of σ_0.2(T) at temperatures 4.2–20 K for CoCrFeMnNiV_0.2, and at 80–150 K for CoCrFeMnNiV_0.5 are found, which indicate at the occurrence of nonthermal inertial dislocation movement.