Thallium and arsenic incorporation in roméite group minerals

  • Đorđević, T. (Selected presenter)
  • Michael Stöger-Pollach (Contributor)
  • Sabine W. Schwarz (Speaker)

Activity: Talks and presentationsPoster presentationScience to Science

Description

Romeite group minerals (RGM) are oxides, which belong to the large pyrochlore supergroup of minerals. The general formula of the pyrochlore supergroup is A2B2X6Y (A = Na, Ca, Ag, Mn, Sr, Ba, Fe(II), Pb, Sn(II), Sb(III), Bi(III), Y, REE, Sc, U, Th, □ and H20, B = Ta, Nb, Ti, Sb(V), W, V(V), Sn(IV), Zr, Hf, Fe(III), Mg, Al, and Si, X = 0, 0H, or F and Y = (0H)–, F–, 02–, □, H20, or even large cations, such as K, Rb, Cs). The crystal structure of RGM is build-up of B06 octahedral framework that forms tunnels along [110] where 8-coordinated A cations and Y anions are hosted. In the RGM, Sb(V) is the dominant cation at the B site, but on the A-site, larger cations can be incorporated where also the ion-exchange can take place. Therefore, RGM are often used for the immobilization of the toxic metals, such as Pb and Sr and have been frequently reported as weathering products in mining wastes and smelting residues resulting from Sb mining activities.
Period24 Aug 202430 Aug 2024
Event titleEMC24: 17th European Microscopy Congress 2024
Event typeConference
LocationCopenhagen, DenmarkShow on map
Degree of RecognitionInternational