TY - JOUR
T1 - Di-[trioctyl-(8-phenyloctyl)-phosphonium] pamoate: synthesis and characterization of a novel, highly hydrophobic ionic liquid for the extraction of scandium, thorium and uranium
AU - Gradwohl, Andreas
AU - Windisch, Jakob
AU - Rosner, Alexander
AU - Heninger, Julia
AU - Fuhrmann, Philipp L.
AU - Wallner, Gabriele
AU - Keppler, Bernhard K.
AU - Kandioller, Wolfgang
AU - Jirsa, Franz
N1 - Publisher Copyright:
Copyright © 2024 Gradwohl, Windisch, Rosner, Heninger, Fuhrmann, Wallner, Keppler, Kandioller and Jirsa.
Accession Number
WOS:001367878400001
PubMed ID
39628988
PY - 2024
Y1 - 2024
N2 - We synthesized and characterized a novel, task-specific ionic liquid for metal extraction with considerably reduced leaching behavior compared to similar, phosphonium-based ionic liquids. The synthesis involves the design of the novel compound [TOPP]2[PAM] featuring both a highly hydrophobic cation and a functional anion. The characterization of the novel ionic liquid confirmed the formation of the desired structure and sufficient purity. The high viscosity of [TOPP]2[PAM] is responsible for the comparably high working temperature of 50°C. Extraction experiments demonstrated the suitability of [TOPP]2[PAM] for extracting Sc, Th and U from aqueous matrices, whereby extraction efficacies of 87.3% ± 9.1% (Sc), 95.8% ± 2.3% (Th) and 92.7% ± 0.3% (U) were achieved over 24 h. Furthermore, Sc could be separated to a high degree via selective extraction from Th as well as from the rare earth elements Y, La, Ce, Nd, Eu, Ho and Lu. Th was separated from La, Ce, Nd, Eu, Ho and Lu at pH 1.00. During all extraction experiments, leaching into the aqueous extraction matrix peaked at only 0.134% ± 0.011% after 24 h. The loading capacities for [TOPP]2[PAM] differed between the investigated metals, the highest values being achieved for U. After extraction, 82.7% ± 2.8% of the extracted Sc could be recovered from the IL using nitric acid (10%), but less of Th and U.
AB - We synthesized and characterized a novel, task-specific ionic liquid for metal extraction with considerably reduced leaching behavior compared to similar, phosphonium-based ionic liquids. The synthesis involves the design of the novel compound [TOPP]2[PAM] featuring both a highly hydrophobic cation and a functional anion. The characterization of the novel ionic liquid confirmed the formation of the desired structure and sufficient purity. The high viscosity of [TOPP]2[PAM] is responsible for the comparably high working temperature of 50°C. Extraction experiments demonstrated the suitability of [TOPP]2[PAM] for extracting Sc, Th and U from aqueous matrices, whereby extraction efficacies of 87.3% ± 9.1% (Sc), 95.8% ± 2.3% (Th) and 92.7% ± 0.3% (U) were achieved over 24 h. Furthermore, Sc could be separated to a high degree via selective extraction from Th as well as from the rare earth elements Y, La, Ce, Nd, Eu, Ho and Lu. Th was separated from La, Ce, Nd, Eu, Ho and Lu at pH 1.00. During all extraction experiments, leaching into the aqueous extraction matrix peaked at only 0.134% ± 0.011% after 24 h. The loading capacities for [TOPP]2[PAM] differed between the investigated metals, the highest values being achieved for U. After extraction, 82.7% ± 2.8% of the extracted Sc could be recovered from the IL using nitric acid (10%), but less of Th and U.
KW - green solvents
KW - ionic liquid
KW - leaching
KW - REE separation
KW - selective extraction
KW - task-specific
UR - http://www.scopus.com/inward/record.url?scp=85211112426&partnerID=8YFLogxK
U2 - 10.3389/fchem.2024.1502232
DO - 10.3389/fchem.2024.1502232
M3 - Article
AN - SCOPUS:85211112426
SN - 2296-2646
VL - 12
JO - Frontiers in Chemistry
JF - Frontiers in Chemistry
M1 - 1502232
ER -