Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions

A. P. Praplan (Corresponding author), S. Schobesberger, F. Bianchi, M. P. Rissanen, M. Ehn, T. Jokinen, H. Junninen, A. Adamov, A. Amorim, J. Dommen, J. Duplissy, J. Hakala, A. Hansel, M. Heinritzi, J. Kangasluoma, J. Kirkby, M. Krapf, A. Kürten, K. Lehtipalo, F. RiccobonoL. Rondo, N. Sarnela, M. Simon, A. Tome, J. Troestl, P. M. Winkler, C. Williamson, P. Ye, J. Curtius, U. Baltensperger, N. M. Donahue, M. Kulmala, D. R. Worsnop

Publications: Contribution to journalArticlePeer Reviewed

Abstract

This study presents the difference between oxidised organic compounds formed by alpha-pinene oxidation under various conditions in the CLOUD environmental chamber: (1) pure ozonolysis (in the presence of hydrogen as hydroxyl radical (OH) scavenger) and (2) OH oxidation (initiated by nitrous acid (HONO) photolysis by ultraviolet light) in the absence of ozone.
We discuss results from three Atmospheric Pressure interface Time-of-Flight (APi-TOF) mass spectrometers measuring simultaneously the composition of naturally charged as well as neutral species (via chemical ionisation with nitrate). Natural chemical ionisation takes place in the CLOUD chamber and organic oxidised compounds form clusters with nitrate, bisulfate, bisulfate/sulfuric acid clusters, ammonium, and dimethylaminium, or get protonated. The results from this study show that this process is selective for various oxidised organic compounds with low molar mass and ions, so that in order to obtain a comprehensive picture of the elemental composition of oxidation products and their clustering behaviour, several instruments must be used. We compare oxidation products containing 10 and 20 carbon atoms and show that highly oxidised organic compounds are formed in the early stages of the oxidation.
Original languageEnglish
Pages (from-to)4145-4159
Number of pages15
JournalAtmospheric Chemistry and Physics
Volume15
Issue number8
DOIs
Publication statusPublished - 22 Apr 2015

Austrian Fields of Science 2012

  • 103037 Environmental physics
  • 103039 Aerosol physics

Keywords

  • SECONDARY ORGANIC AEROSOL
  • CONTROLLED CHEMICAL CONDITIONS
  • HIGH-NOX ENVIRONMENTS
  • SULFURIC-ACID
  • PARTICLE FORMATION
  • MASS-SPECTROMETRY
  • ATMOSPHERIC CONDITIONS
  • BOREAL FOREST
  • NUCLEATION
  • PHOTOOXIDATION

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