Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry

D. Henriques; V. Motalov; L. Bencze; Siegfried Fürtauer; H. Flandorfer; T. Markus

doi:10.1016/j.jallcom.2016.06.091

Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry

D. Henriques (Corresponding author), V. Motalov, L. Bencze, Siegfried Fürtauer, H. Flandorfer, T. Markus

Department of Functional Materials and Catalysis

Publications: Contribution to journal › Article › Peer Reviewed

Abstract

Thermodynamic data of seven Cu-Li-Sn alloys were determined by the Knudsen Effusion Mass Spectrometry (KEMS) for the solid, solid-liquid or liquid region. Thermodynamic activities of components, enthalpies and entropies of mixing were calculated in the temperature range of 623-933 K. The intermetallic phases Cu ₆Li ₃Sn ₄(s), CuLi ₂Sn ₂(s), and CuLi ₃Sn(s) have been described in literature quite recently. These phases were observed by powder X-ray diffraction (XRD) measurements after sample preparation. The thermodynamic data obtained by KEMS and the crystallographic data will enhance the available information for calculating the phase diagram for the ternary Cu-Li-Sn system by CALPHAD approach.

Original language	English
Pages (from-to)	306-311
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	687
DOIs	https://doi.org/10.1016/j.jallcom.2016.06.091
Publication status	Published - 5 Dec 2016

Austrian Fields of Science 2012

104003 Inorganic chemistry
104017 Physical chemistry
104011 Materials chemistry

Keywords

Cu-Li-Sn
Knudsen Effusion Mass Spectrometry
Thermodynamic properties
CALPHAD
Lithium-ion batteries
LITHIUM-ION BATTERIES
PHASE-DIAGRAM
ANODE MATERIALS
FILM ELECTRODE
COMPOSITE
LI2CUSN2
ENERGY

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jallcom.2016.06.091

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title = "Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry",

abstract = "Thermodynamic data of seven Cu-Li-Sn alloys were determined by the Knudsen Effusion Mass Spectrometry (KEMS) for the solid, solid-liquid or liquid region. Thermodynamic activities of components, enthalpies and entropies of mixing were calculated in the temperature range of 623-933 K. The intermetallic phases Cu 6Li 3Sn 4(s), CuLi 2Sn 2(s), and CuLi 3Sn(s) have been described in literature quite recently. These phases were observed by powder X-ray diffraction (XRD) measurements after sample preparation. The thermodynamic data obtained by KEMS and the crystallographic data will enhance the available information for calculating the phase diagram for the ternary Cu-Li-Sn system by CALPHAD approach. ",

keywords = "Cu-Li-Sn, Knudsen Effusion Mass Spectrometry, Thermodynamic properties, CALPHAD, Lithium-ion batteries, LITHIUM-ION BATTERIES, PHASE-DIAGRAM, ANODE MATERIALS, FILM ELECTRODE, COMPOSITE, LI2CUSN2, ENERGY",

author = "D. Henriques and V. Motalov and L. Bencze and Siegfried F{\"u}rtauer and H. Flandorfer and T. Markus",

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year = "2016",

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doi = "10.1016/j.jallcom.2016.06.091",

language = "English",

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T1 - Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry

AU - Henriques, D.

AU - Motalov, V.

AU - Bencze, L.

AU - Fürtauer, Siegfried

AU - Flandorfer, H.

AU - Markus, T.

PY - 2016/12/5

Y1 - 2016/12/5

N2 - Thermodynamic data of seven Cu-Li-Sn alloys were determined by the Knudsen Effusion Mass Spectrometry (KEMS) for the solid, solid-liquid or liquid region. Thermodynamic activities of components, enthalpies and entropies of mixing were calculated in the temperature range of 623-933 K. The intermetallic phases Cu 6Li 3Sn 4(s), CuLi 2Sn 2(s), and CuLi 3Sn(s) have been described in literature quite recently. These phases were observed by powder X-ray diffraction (XRD) measurements after sample preparation. The thermodynamic data obtained by KEMS and the crystallographic data will enhance the available information for calculating the phase diagram for the ternary Cu-Li-Sn system by CALPHAD approach.

AB - Thermodynamic data of seven Cu-Li-Sn alloys were determined by the Knudsen Effusion Mass Spectrometry (KEMS) for the solid, solid-liquid or liquid region. Thermodynamic activities of components, enthalpies and entropies of mixing were calculated in the temperature range of 623-933 K. The intermetallic phases Cu 6Li 3Sn 4(s), CuLi 2Sn 2(s), and CuLi 3Sn(s) have been described in literature quite recently. These phases were observed by powder X-ray diffraction (XRD) measurements after sample preparation. The thermodynamic data obtained by KEMS and the crystallographic data will enhance the available information for calculating the phase diagram for the ternary Cu-Li-Sn system by CALPHAD approach.

KW - Cu-Li-Sn

KW - Knudsen Effusion Mass Spectrometry

KW - Thermodynamic properties

KW - CALPHAD

KW - Lithium-ion batteries

KW - LITHIUM-ION BATTERIES

KW - PHASE-DIAGRAM

KW - ANODE MATERIALS

KW - FILM ELECTRODE

KW - COMPOSITE

KW - LI2CUSN2

KW - ENERGY

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DO - 10.1016/j.jallcom.2016.06.091

M3 - Article

SN - 0925-8388

VL - 687

SP - 306

EP - 311

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry

Abstract

Austrian Fields of Science 2012

Keywords

UN SDGs

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