Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH
            2I

Laura Ielo; Laura Castoldi; Saad Touqeer; Jessica Lombino; Alexander Roller; Cristina Prandi; Wolfgang Holzer; Vittorio Pace

doi:10.1002/anie.202007954

Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH ₂I

Laura Ielo, Laura Castoldi, Saad Touqeer, Jessica Lombino, Alexander Roller, Cristina Prandi, Wolfgang Holzer, Vittorio Pace (Corresponding author)

Publications: Contribution to journal › Article › Peer Reviewed

Original language	English
Pages (from-to)	20852-20857
Number of pages	6
Journal	Angewandte Chemie (International Edition)
Volume	59
Issue number	47
DOIs	https://doi.org/10.1002/anie.202007954
Publication status	Published - 16 Nov 2020

Austrian Fields of Science 2012

104003 Inorganic chemistry
104024 X-ray structural analysis

Keywords

carbenoids
chemoselectivity
homologation
imines
metalation
BORONIC ESTERS
COMPLEXES
STEREODYNAMICS
STABILITY
AMIDES

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10.1002/anie.202007954

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Ielo, L., Castoldi, L., Touqeer, S., Lombino, J., Roller, A., Prandi, C., Holzer, W., & Pace, V. (2020). Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH ₂I. Angewandte Chemie (International Edition), 59(47), 20852-20857. https://doi.org/10.1002/anie.202007954

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title = "Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH 2I",

keywords = "carbenoids, chemoselectivity, homologation, imines, metalation, BORONIC ESTERS, COMPLEXES, STEREODYNAMICS, STABILITY, AMIDES",

author = "Laura Ielo and Laura Castoldi and Saad Touqeer and Jessica Lombino and Alexander Roller and Cristina Prandi and Wolfgang Holzer and Vittorio Pace",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH GmbH",

year = "2020",

month = nov,

day = "16",

doi = "10.1002/anie.202007954",

language = "English",

volume = "59",

pages = "20852--20857",

journal = "Angewandte Chemie (International Edition)",

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Ielo, L, Castoldi, L, Touqeer, S, Lombino, J, Roller, A, Prandi, C, Holzer, W & Pace, V 2020, 'Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH ₂I', Angewandte Chemie (International Edition), vol. 59, no. 47, pp. 20852-20857. https://doi.org/10.1002/anie.202007954

Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH ₂I. / Ielo, Laura; Castoldi, Laura; Touqeer, Saad et al.
In: Angewandte Chemie (International Edition), Vol. 59, No. 47, 16.11.2020, p. 20852-20857.

Publications: Contribution to journal › Article › Peer Reviewed

TY - JOUR

T1 - Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates

T2 - Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH 2I

AU - Ielo, Laura

AU - Castoldi, Laura

AU - Touqeer, Saad

AU - Lombino, Jessica

AU - Roller, Alexander

AU - Prandi, Cristina

AU - Holzer, Wolfgang

AU - Pace, Vittorio

PY - 2020/11/16

Y1 - 2020/11/16

KW - carbenoids

KW - chemoselectivity

KW - homologation

KW - imines

KW - metalation

KW - BORONIC ESTERS

KW - COMPLEXES

KW - STEREODYNAMICS

KW - STABILITY

KW - AMIDES

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DO - 10.1002/anie.202007954

M3 - Article

SN - 1433-7851

VL - 59

SP - 20852

EP - 20857

JO - Angewandte Chemie (International Edition)

JF - Angewandte Chemie (International Edition)

IS - 47

ER -

Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-β-Diketiminates and the Dual Role of LiCH ₂I

Austrian Fields of Science 2012

Keywords

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