Lead-free Solder Materials: Experimental Enthalpies of Mixing in Quaternary Liquid Ag-In-Pd-Sn Alloys

Christoph Luef (Corresponding author), Hans Flandorfer, Herbert Ipser

Publications: Contribution to journalArticlePeer Reviewed

Abstract

The partial and integral enthalpies of mixing of liquid Ag-In-Sn and Ag-In-Pd-Sn alloys were determined at 900°C by a drop calorimetric technique using a Calvet-type microcalorimeter. The binary interaction parameters of Ag-In and the ternary interaction parameters of Ag-In-Pd and Ag-In-Sn were fitted based on both literature data and the authors' measurements employing the Redlich-Kister-Muggiano model for substitutional solutions. Furthermore, it was investigated whether additional quaternary interactions have to be taken into account for the description of the enthalpy of mixing in the Ag-In-Pd-Sn system.
Original languageEnglish
Pages (from-to)1273-1277
Number of pages5
JournalMetallurgical and Materials Transactions A - Physical Metallurgy and Materials Science
Volume36
Issue number5
Publication statusPublished - 2005

Austrian Fields of Science 2012

  • 104003 Inorganic chemistry
  • 104011 Materials chemistry

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