Liquid Co-Sn alloys at high temperatures: structure and physical properties

Yuriy Plevachuk; Vasyl Sklyarchuk; Ihor Shtablavyi; Stepan Mudry; Juergen Brillo; Hidekazu Kobatake; Andriy Yakymovych; Siegfried Fürtauer; Barbara Janina Skolyszewska-Kühberger; Klaus Richter; Hans Flandorfer; Herbert Ipser

doi:10.1080/00319104.2015.1115327

Liquid Co-Sn alloys at high temperatures: structure and physical properties

Yuriy Plevachuk, Vasyl Sklyarchuk, Ihor Shtablavyi, Stepan Mudry, Juergen Brillo, Hidekazu Kobatake, Andriy Yakymovych (Corresponding author), Siegfried Fürtauer, Barbara Janina Skolyszewska-Kühberger, Klaus Richter, Hans Flandorfer, Herbert Ipser

Publications: Contribution to journal › Article › Peer Reviewed

Abstract

The Co-Sn system is an important subsystem for Sn-based anode materials of lithium-ion batteries. Experimental results on the physical-chemical properties of this system in the liquid state, however, are rather sparse. In this work, the atomic structure and structure-sensitive thermophysical properties (viscosity, electrical resistivity, and thermoelectric power) of liquid Co-Sn alloys were investigated in a wide temperature range with special attention to the melting-solidification region. The obtained experimental results were combined with differential thermal analysis (DTA) data in order to verify the liquidus curve in the Sn-rich part of the Co-Sn phase diagram.

Original language	English
Pages (from-to)	440-453
Number of pages	14
Journal	Physics and Chemistry of Liquids: an international journal
Volume	54
Issue number	4
DOIs	https://doi.org/10.1080/00319104.2015.1115327
Publication status	Published - 2016

Austrian Fields of Science 2012

104003 Inorganic chemistry
104017 Physical chemistry
104011 Materials chemistry

Keywords

Intermetallic alloys
X-ray diffraction
electrical resistivity
viscosity
differential thermal analysis (DTA)
LITHIUM-ION BATTERIES
COBALT-TIN ALLOYS
ELECTRICAL-CONDUCTIVITY
INTERFACIAL REACTIONS
SYSTEM
VISCOSITY
RESISTIVITY
ENTHALPY
ANODES
COBALT-TIN
LITHIUM ION BATTERIES

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/00319104.2015.1115327

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Plevachuk, Y., Sklyarchuk, V., Shtablavyi, I., Mudry, S., Brillo, J., Kobatake, H., Yakymovych, A., Fürtauer, S., Skolyszewska-Kühberger, B. J., Richter, K., Flandorfer, H., & Ipser, H. (2016). Liquid Co-Sn alloys at high temperatures: structure and physical properties. Physics and Chemistry of Liquids: an international journal, 54(4), 440-453. https://doi.org/10.1080/00319104.2015.1115327

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abstract = "The Co-Sn system is an important subsystem for Sn-based anode materials of lithium-ion batteries. Experimental results on the physical-chemical properties of this system in the liquid state, however, are rather sparse. In this work, the atomic structure and structure-sensitive thermophysical properties (viscosity, electrical resistivity, and thermoelectric power) of liquid Co-Sn alloys were investigated in a wide temperature range with special attention to the melting-solidification region. The obtained experimental results were combined with differential thermal analysis (DTA) data in order to verify the liquidus curve in the Sn-rich part of the Co-Sn phase diagram.",

keywords = "Intermetallic alloys, X-ray diffraction, electrical resistivity, viscosity, differential thermal analysis (DTA), LITHIUM-ION BATTERIES, COBALT-TIN ALLOYS, ELECTRICAL-CONDUCTIVITY, INTERFACIAL REACTIONS, SYSTEM, VISCOSITY, RESISTIVITY, ENTHALPY, ANODES, COBALT-TIN, LITHIUM ION BATTERIES",

author = "Yuriy Plevachuk and Vasyl Sklyarchuk and Ihor Shtablavyi and Stepan Mudry and Juergen Brillo and Hidekazu Kobatake and Andriy Yakymovych and Siegfried F{\"u}rtauer and Skolyszewska-K{\"u}hberger, {Barbara Janina} and Klaus Richter and Hans Flandorfer and Herbert Ipser",

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Plevachuk, Y, Sklyarchuk, V, Shtablavyi, I, Mudry, S, Brillo, J, Kobatake, H, Yakymovych, A, Fürtauer, S, Skolyszewska-Kühberger, BJ, Richter, K , Flandorfer, H & Ipser, H 2016, 'Liquid Co-Sn alloys at high temperatures: structure and physical properties', Physics and Chemistry of Liquids: an international journal, vol. 54, no. 4, pp. 440-453. https://doi.org/10.1080/00319104.2015.1115327

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AU - Plevachuk, Yuriy

AU - Sklyarchuk, Vasyl

AU - Shtablavyi, Ihor

AU - Mudry, Stepan

AU - Brillo, Juergen

AU - Kobatake, Hidekazu

AU - Yakymovych, Andriy

AU - Fürtauer, Siegfried

AU - Skolyszewska-Kühberger, Barbara Janina

AU - Richter, Klaus

AU - Flandorfer, Hans

AU - Ipser, Herbert

PY - 2016

Y1 - 2016

N2 - The Co-Sn system is an important subsystem for Sn-based anode materials of lithium-ion batteries. Experimental results on the physical-chemical properties of this system in the liquid state, however, are rather sparse. In this work, the atomic structure and structure-sensitive thermophysical properties (viscosity, electrical resistivity, and thermoelectric power) of liquid Co-Sn alloys were investigated in a wide temperature range with special attention to the melting-solidification region. The obtained experimental results were combined with differential thermal analysis (DTA) data in order to verify the liquidus curve in the Sn-rich part of the Co-Sn phase diagram.

AB - The Co-Sn system is an important subsystem for Sn-based anode materials of lithium-ion batteries. Experimental results on the physical-chemical properties of this system in the liquid state, however, are rather sparse. In this work, the atomic structure and structure-sensitive thermophysical properties (viscosity, electrical resistivity, and thermoelectric power) of liquid Co-Sn alloys were investigated in a wide temperature range with special attention to the melting-solidification region. The obtained experimental results were combined with differential thermal analysis (DTA) data in order to verify the liquidus curve in the Sn-rich part of the Co-Sn phase diagram.

KW - Intermetallic alloys

KW - X-ray diffraction

KW - electrical resistivity

KW - viscosity

KW - differential thermal analysis (DTA)

KW - LITHIUM-ION BATTERIES

KW - COBALT-TIN ALLOYS

KW - ELECTRICAL-CONDUCTIVITY

KW - INTERFACIAL REACTIONS

KW - SYSTEM

KW - VISCOSITY

KW - RESISTIVITY

KW - ENTHALPY

KW - ANODES

KW - COBALT-TIN

KW - LITHIUM ION BATTERIES

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DO - 10.1080/00319104.2015.1115327

M3 - Article

SN - 0031-9104

VL - 54

SP - 440

EP - 453

JO - Physics and Chemistry of Liquids: an international journal

JF - Physics and Chemistry of Liquids: an international journal

IS - 4

ER -

Liquid Co-Sn alloys at high temperatures: structure and physical properties

Abstract

Austrian Fields of Science 2012

Keywords

UN SDGs

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