TY - JOUR
T1 - On the coordination properties of new bicyclophosphite-carbohydrates
AU - Nazarov, Alexey
AU - Koroteev, Mikhail P.
AU - Hartinger, Christian
AU - Keppler, Bernhard
AU - Nifant'ev, Eduard E.
N1 - DOI: 10.1007/s00706-004-0238-y
Affiliations: Moscow Pedagogical State University, Chemistry Department, Moscow 119021, Russian Federation; Institute of Inorganic Chemistry, University of Vienna, A-1090 Vienna, Austria
Adressen: Nazarov, A.A.; Moscow Pedagogical State University; Chemistry Department Moscow 119021, Russian Federation; email: [email protected]
Source-File: ChemieErgScopus.csv
Import aus Scopus: 2-s2.0-13444311815
Importdatum: 09.01.2007 14:09:26
12.02.2008: Datenanforderung 2112 (Import Sachbearbeiter)
09.02.2010: Datenanforderung UNIVIS-DATEN-DAT.RA-2 (Import Sachbearbeiter)
PY - 2005
Y1 - 2005
N2 - The coordination behavior of newly developed bicyclophosphite ligands toward Mo(0), Rh(I), and Pt(II) was studied. Reactions at different ratios of metal to ligand were done. It was found that the ligands act as monodentate ones and form with hexacarbonylmolybdenum(0) complexes with the general formula Mo(CO)5L by replacing only one carbonyl ligand. Coordination experiments toward acetylacetonatodicarbonylrhodium(I) resulted in the formation of undefined compounds. Toward dichlorocyclooctadienylplatinum(II) the monomeric phosphorus ligands act as monodentate ligands forming complexes of the general structure cis-PtCl2L2. All the synthesized platinum-complexes possess cis-configuration (proven by 31P NMR). The corresponding coordination compounds were isolated and characterized by elemental analyses and 1H, 13C, and 31P NMR. ΠSpringer-Verlag 2004.
AB - The coordination behavior of newly developed bicyclophosphite ligands toward Mo(0), Rh(I), and Pt(II) was studied. Reactions at different ratios of metal to ligand were done. It was found that the ligands act as monodentate ones and form with hexacarbonylmolybdenum(0) complexes with the general formula Mo(CO)5L by replacing only one carbonyl ligand. Coordination experiments toward acetylacetonatodicarbonylrhodium(I) resulted in the formation of undefined compounds. Toward dichlorocyclooctadienylplatinum(II) the monomeric phosphorus ligands act as monodentate ligands forming complexes of the general structure cis-PtCl2L2. All the synthesized platinum-complexes possess cis-configuration (proven by 31P NMR). The corresponding coordination compounds were isolated and characterized by elemental analyses and 1H, 13C, and 31P NMR. ΠSpringer-Verlag 2004.
M3 - Article
SN - 0026-9247
VL - 136
SP - 137
EP - 146
JO - Monatshefte für Chemie
JF - Monatshefte für Chemie
IS - 2
ER -