Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors

Yan Z. Voloshin; Semyon V. Dudkin; Svetlana A. Belova; Daniel Gherca; Dumitru Samohvalov; Corina-Mihaela Manta; Maria-Andreea Lungan; Samuel M. Meier-Menches; Peter Rapta; Denisa Darvasiova; Michal Malcek; Armando J. L. Pombeiro; Luisa M. D. R. S. Martins; Vladimir B. Arion

doi:10.3390/molecules26020336

Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors

Yan Z. Voloshin
, Semyon V. Dudkin
, Svetlana A. Belova
, Daniel Gherca
, Dumitru Samohvalov
, Corina-Mihaela Manta
, Maria-Andreea Lungan
, Samuel M. Meier-Menches
, Peter Rapta (Corresponding author)
, Denisa Darvasiova
, Michal Malcek
, Armando J. L. Pombeiro
, Luisa M. D. R. S. Martins (Corresponding author)
, Vladimir B. Arion (Corresponding author)

Publications: Contribution to journal › Article › Peer Reviewed

Original language	English
Article number	336
Number of pages	19
Journal	Molecules
Volume	26
Issue number	2
DOIs	https://doi.org/10.3390/molecules26020336
Publication status	Published - Jan 2021

Funding

This work was supported by the European Commission H2020-MSCA-RISE-2017 Grant number, 778245, by the Slovak Grant Agencies APVV (contract Nos. APVV-15-0053, APVV-15-0079, APVV-19-0024 and DS-FR-19-0035) and VEGA (contracts No. 1/0139/20, 1/0718/19, 1/0504/20 and 1/0466/18), and by the Fundacao para a Ciencia e Tecnologia (FCT) and project UIDB/00100/2020 of Centro de Quimica Estrutural, Portugal. M.M is grateful to the HPC center at the Slovak University of Technology in Bratislava, which is a part of the Slovak Infrastructure of High Performance Computing (SIVVP project, ITMS code 26230120002, funded by the European region development funds) for the computational time and resources made available. P.R. thanks the Ministry of Education, Science, Research and Sport of the Slovak Republic for funding within the scheme "Excellent research teams". The synthesis of hybrid complexes and their precursor was supported by the Russian Science Foundation (grant 17-13-01468). Y.Z.V., S.V.D. and S.A.B. also thank the Russian Foundation for Basic Research (grants 18-29-23007 and 19-03-00357) for support of the spectral studies. The initial optical experiments were supported by INEOS RAS state assignment.

Austrian Fields of Science 2012

104003 Inorganic chemistry
104017 Physical chemistry
106002 Biochemistry
106023 Molecular biology

Keywords

clathrochelates
phthalocyanines
zirconium(IV)
hafnium(IV)
nickel(II)
iron(II)
spectroelectrochemistry
homogeneous catalysis
oxidation reactions
DFT calculations
Hafnium(IV)
Spectro-electrochemistry
Iron(II)
Nickel(II)
Homogeneous catalysis
Clathrochelates
Zirconium(IV)
Oxidation reactions
Phthalocyanines

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10.3390/molecules26020336Licence: CC BY 4.0

https://phaidra.univie.ac.at/o:1543376Licence: CC BY 4.0

Cite this

Voloshin, Y. Z., Dudkin, S. V., Belova, S. A., Gherca, D., Samohvalov, D., Manta, C.-M., Lungan, M.-A., Meier-Menches, S. M., Rapta, P., Darvasiova, D., Malcek, M., Pombeiro, A. J. L., Martins, L. M. D. R. S., & Arion, V. B. (2021). Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors. Molecules, 26(2), Article 336. https://doi.org/10.3390/molecules26020336

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title = "Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors",

keywords = "clathrochelates, phthalocyanines, zirconium(IV), hafnium(IV), nickel(II), iron(II), spectroelectrochemistry, homogeneous catalysis, oxidation reactions, DFT calculations, Hafnium(IV), Spectro-electrochemistry, Iron(II), Nickel(II), Homogeneous catalysis, Clathrochelates, Zirconium(IV), Oxidation reactions, Phthalocyanines",

author = "Voloshin, \{Yan Z.\} and Dudkin, \{Semyon V.\} and Belova, \{Svetlana A.\} and Daniel Gherca and Dumitru Samohvalov and Corina-Mihaela Manta and Maria-Andreea Lungan and Meier-Menches, \{Samuel M.\} and Peter Rapta and Denisa Darvasiova and Michal Malcek and Pombeiro, \{Armando J. L.\} and Martins, \{Luisa M. D. R. S.\} and Arion, \{Vladimir B.\}",

note = "Accession Number: WOS:000611480500001 PubMed ID: 33440755 Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = jan,

doi = "10.3390/molecules26020336",

language = "English",

volume = "26",

journal = "Molecules",

issn = "1420-3049",

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Voloshin, YZ, Dudkin, SV, Belova, SA, Gherca, D, Samohvalov, D, Manta, C-M, Lungan, M-A, Meier-Menches, SM, Rapta, P, Darvasiova, D, Malcek, M, Pombeiro, AJL, Martins, LMDRS & Arion, VB 2021, 'Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors', Molecules, vol. 26, no. 2, 336. https://doi.org/10.3390/molecules26020336

Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors. / Voloshin, Yan Z.; Dudkin, Semyon V.; Belova, Svetlana A. et al.
In: Molecules, Vol. 26, No. 2, 336, 01.2021.

Publications: Contribution to journal › Article › Peer Reviewed

TY - JOUR

T1 - Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors

AU - Voloshin, Yan Z.

AU - Dudkin, Semyon V.

AU - Belova, Svetlana A.

AU - Gherca, Daniel

AU - Samohvalov, Dumitru

AU - Manta, Corina-Mihaela

AU - Lungan, Maria-Andreea

AU - Meier-Menches, Samuel M.

AU - Rapta, Peter

AU - Darvasiova, Denisa

AU - Malcek, Michal

AU - Pombeiro, Armando J. L.

AU - Martins, Luisa M. D. R. S.

AU - Arion, Vladimir B.

PY - 2021/1

Y1 - 2021/1

KW - clathrochelates

KW - phthalocyanines

KW - zirconium(IV)

KW - hafnium(IV)

KW - nickel(II)

KW - iron(II)

KW - spectroelectrochemistry

KW - homogeneous catalysis

KW - oxidation reactions

KW - DFT calculations

KW - Hafnium(IV)

KW - Spectro-electrochemistry

KW - Iron(II)

KW - Nickel(II)

KW - Homogeneous catalysis

KW - Clathrochelates

KW - Zirconium(IV)

KW - Oxidation reactions

KW - Phthalocyanines

UR - https://www.scopus.com/pages/publications/85099999745

U2 - 10.3390/molecules26020336

DO - 10.3390/molecules26020336

M3 - Article

SN - 1420-3049

VL - 26

JO - Molecules

JF - Molecules

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M1 - 336

ER -

Spectroelectrochemical Properties and Catalytic Activity in Cyclohexane Oxidation of the Hybrid Zr/Hf-Phthalocyaninate-Capped Nickel(II) and Iron(II) tris-Pyridineoximates and Their Precursors

Funding

Austrian Fields of Science 2012

Keywords

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