TY - JOUR
T1 - Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior
AU - Kogelnig, Daniel
AU - Stojanovic, Anja
AU - von der Kammer, Frank
AU - Terzieff, Peter
AU - Galanski, Mathea Sophia
AU - Jirsa, Franz
AU - Krachler, Regina
AU - Hofmann, Thilo
AU - Keppler, Bernhard
PY - 2010
Y1 - 2010
N2 - The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.
AB - The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.
U2 - 10.1016/j.inoche.2010.08.023
DO - 10.1016/j.inoche.2010.08.023
M3 - Article
VL - 13
SP - 1485
EP - 1488
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
SN - 1387-7003
IS - 12
ER -