Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior

Daniel Kogelnig; Anja Stojanovic; Frank von der Kammer; Peter Terzieff; Mathea Sophia Galanski; Franz Jirsa; Regina Krachler; Thilo Hofmann; Bernhard Keppler

doi:10.1016/j.inoche.2010.08.023

Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior

Daniel Kogelnig (Corresponding author)
, Anja Stojanovic
, Frank von der Kammer
, Peter Terzieff
, Mathea Sophia Galanski
, Franz Jirsa
, Regina Krachler
, Thilo Hofmann
, Bernhard Keppler

Publications: Contribution to journal › Article › Peer Reviewed

Abstract

The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.

Original language	English
Pages (from-to)	1485-1488
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2010.08.023
Publication status	Published - 2010

Austrian Fields of Science 2012

104003 Inorganic chemistry

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10.1016/j.inoche.2010.08.023

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title = "Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior",

abstract = "The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.",

author = "Daniel Kogelnig and Anja Stojanovic and \{von der Kammer\}, Frank and Peter Terzieff and Galanski, \{Mathea Sophia\} and Franz Jirsa and Regina Krachler and Thilo Hofmann and Bernhard Keppler",

year = "2010",

doi = "10.1016/j.inoche.2010.08.023",

language = "English",

volume = "13",

pages = "1485--1488",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

number = "12",

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TY - JOUR

T1 - Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior

AU - Kogelnig, Daniel

AU - Stojanovic, Anja

AU - von der Kammer, Frank

AU - Terzieff, Peter

AU - Galanski, Mathea Sophia

AU - Jirsa, Franz

AU - Krachler, Regina

AU - Hofmann, Thilo

AU - Keppler, Bernhard

PY - 2010

Y1 - 2010

N2 - The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.

AB - The magnetic behavior of a binary salt of tricaprylylmethylammonium tetrachloroferrate and tricaprylylmethylammonium chloride, [A336][FeCl4](0.73)[Cl](0.27), was evaluated. With a magnetic susceptibility of 0.011 emu mol(-1) this binary salt exhibited a remarkable response to an external magnetic field. Dynamic light scattering (DLS) measurements allowed to study the aggregation behavior of [A336][FeCl4](0.73)[Cl](0.27) as well as of further magnetic ionic liquids [PR6,6,6,14][FeCl4] and (BMIM)[FeCl4] in ethylacetate and ethanol.

U2 - 10.1016/j.inoche.2010.08.023

DO - 10.1016/j.inoche.2010.08.023

M3 - Article

SN - 1387-7003

VL - 13

SP - 1485

EP - 1488

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Tetrachloroferrate containing ionic liquids: Magnetic- and aggregation behavior

Abstract

Austrian Fields of Science 2012

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