The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys

Yu Plevachuk; A. Yakymovych; Siegfried Fürtauer; H. Ipser; H. Flandorfer

doi:10.1007/s11669-014-0288-8

The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys

Yu Plevachuk, A. Yakymovych (Corresponding author), Siegfried Fürtauer, H. Ipser, H. Flandorfer

Department of Functional Materials and Catalysis

Publications: Contribution to journal › Article › Peer Reviewed

Abstract

The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections x _Ni/x _Sn ≈ 1:9, x _Ni/x _Sn ≈ 1:6 at 1073 K and along two sections x _Sn/x _Zn ≈ 9:1, x _Sn/x _Zn ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. -20000 J mol ^-1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol ^-1 is equal to the maximum in the binary Sn-Zn system.

Original language	English
Pages (from-to)	359-368
Number of pages	10
Journal	Journal of Phase Equilibria and Diffusion
Volume	35
Issue number	4
DOIs	https://doi.org/10.1007/s11669-014-0288-8
Publication status	Published - Aug 2014

Austrian Fields of Science 2012

104017 Physical chemistry
104011 Materials chemistry

Keywords

calorimetry
enthalpy of mixing
metallic alloys
ternary
PHASE-EQUILIBRIA
THERMODYNAMIC OPTIMIZATION
INTERFACIAL REACTIONS
HIGH-TEMPERATURE
SYSTEM
TIN
LEAD
CU
LEGIERUNGEN
DIAGRAM

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title = "The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys",

abstract = "The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections x Ni/x Sn ≈ 1:9, x Ni/x Sn ≈ 1:6 at 1073 K and along two sections x Sn/x Zn ≈ 9:1, x Sn/x Zn ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. -20000 J mol -1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol -1 is equal to the maximum in the binary Sn-Zn system.",

keywords = "calorimetry, enthalpy of mixing, metallic alloys, ternary, PHASE-EQUILIBRIA, THERMODYNAMIC OPTIMIZATION, INTERFACIAL REACTIONS, HIGH-TEMPERATURE, SYSTEM, TIN, LEAD, CU, LEGIERUNGEN, DIAGRAM",

author = "Yu Plevachuk and A. Yakymovych and Siegfried F{\"u}rtauer and H. Ipser and H. Flandorfer",

note = "Funding Information: This work was performed in the framework of the European Concerted Research Action COST MP0602 project {\textquoteleft}{\textquoteleft}Advanced Solder Materials for High Temperature Application{\textquoteright}{\textquoteright}. Financial support by the Austrian Science Fund (FWF) under Project No. P21507 is gratefully acknowledged. Yu.P. was supported through a Short Term Scientific Mission within COST MP0602. A.Ya. was supported by a Lise Meitner Fellowship of the Austrian Science Fund (FWF, Project No. M1324).",

year = "2014",

month = aug,

doi = "10.1007/s11669-014-0288-8",

language = "English",

volume = "35",

pages = "359--368",

journal = "Journal of Phase Equilibria and Diffusion",

issn = "1547-7037",

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AU - Yakymovych, A.

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AU - Ipser, H.

AU - Flandorfer, H.

N1 - Funding Information: This work was performed in the framework of the European Concerted Research Action COST MP0602 project ‘‘Advanced Solder Materials for High Temperature Application’’. Financial support by the Austrian Science Fund (FWF) under Project No. P21507 is gratefully acknowledged. Yu.P. was supported through a Short Term Scientific Mission within COST MP0602. A.Ya. was supported by a Lise Meitner Fellowship of the Austrian Science Fund (FWF, Project No. M1324).

PY - 2014/8

Y1 - 2014/8

N2 - The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections x Ni/x Sn ≈ 1:9, x Ni/x Sn ≈ 1:6 at 1073 K and along two sections x Sn/x Zn ≈ 9:1, x Sn/x Zn ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. -20000 J mol -1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol -1 is equal to the maximum in the binary Sn-Zn system.

AB - The partial and integral enthalpies of mixing of liquid ternary Ni-Sn-Zn alloys were determined. The system was investigated along two sections x Ni/x Sn ≈ 1:9, x Ni/x Sn ≈ 1:6 at 1073 K and along two sections x Sn/x Zn ≈ 9:1, x Sn/x Zn ≈ 4:1 at 873 K. The integral enthalpy of mixing at each temperature is described using the Redlich-Kister-Muggianu model for substitutional ternary solutions. In addition, the experimental results were compared with data calculated according to the Toop extrapolation model. The minimum integral enthalpy of approx. -20000 J mol -1 corresponds to the minimum in the constituent binary Ni-Sn system, the maximum of approx. 3000 J mol -1 is equal to the maximum in the binary Sn-Zn system.

KW - calorimetry

KW - enthalpy of mixing

KW - metallic alloys

KW - ternary

KW - PHASE-EQUILIBRIA

KW - THERMODYNAMIC OPTIMIZATION

KW - INTERFACIAL REACTIONS

KW - HIGH-TEMPERATURE

KW - SYSTEM

KW - TIN

KW - LEAD

KW - CU

KW - LEGIERUNGEN

KW - DIAGRAM

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DO - 10.1007/s11669-014-0288-8

M3 - Article

SN - 1547-7037

VL - 35

SP - 359

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JO - Journal of Phase Equilibria and Diffusion

JF - Journal of Phase Equilibria and Diffusion

IS - 4

ER -

The Enthalpies of Mixing of Liquid Ni-Sn-Zn Alloys

Abstract

Austrian Fields of Science 2012

Keywords

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